Research Progress
Printable circuits that can work on fabric, plastic and even fruit
Post: 2022-11-04 16:19  View:109

Remember iron-on decals? All you had to do was print something out on special paper with a home printer, then transfer it onto a T-shirt using an iron. Now, scientists have developed a very similar scheme, but instead of family photos or logos, it prints circuitry. The method, reported in ACS Applied Materials & Interfaces, can print functional circuits onto items ranging from ukuleles to teacups.

As electronics continue to evolve, so too do the circuit boards that control them. Most boards used today are rigid, built on solid fiberglass backings. As electronic systems are integrated into floppy and pliable items, such as clothing and soft robots, electronics need to be flexible too. This has led to increased interest in liquid metal circuits, which often include a special alloy of gallium metal that is a liquid at room temperature. One way to make these devices is to print them out with a modified inkjet or 3D printer. But these methods require complicated steps and sophisticated equipment, making the resulting devices expensive and unsuitable for large-scale manufacturing. To make the fabrication process quicker, easier and cheaper, Xian Huang and colleagues wanted to develop a method of creating liquid metal circuitry using a desktop laser printer that could place the electronics onto many types of surfaces.

To create the circuits, the researchers printed out a connected design onto heat-transferrable thermal paper with an ordinary laser printer. The printer laid down a carbon-based toner, which was transferred to a pane of glass by heating it. These toner patterns roughened the surface and created a hydrophobic gap of air between the carbon and the liquid metal. This prevented the metal from sticking when brushed on top, so the electronic ink-based pattern only adhered on the exposed parts of the surface.

This circuit could then be stuck directly to a smooth surface, such as a plastic soda bottle. If the surface was too uneven, like the bumpy skin of an orange, the device was first placed on a piece of flexible plastic, then onto the rougher surface. Regardless of how they were attached, however, the simple electronics all functioned as intended on their various substrates -- from displaying images, to RFID tagging, to sensing temperature and sound. The researchers say that this protocol should greatly expand the applications of liquid metal circuits.

The authors acknowledge funding from the Key Research and Development Program of Zhejiang Province and the National Natural Science Foundation of China.

Figure 1. Thermal transfer-based multisubstrate pervasive printing of liquid metal circuits. (A) Principle and the fabrication process of the liquid meal conductive traces. (i) Design of interfaces with different roughness on the substrates. (ii) Rapid printing through a laser printer on a large area. (iii) Schematics of the entire printing process. (B) Liquid metal patterns on four smooth substrates. (C) Liquid metal patterns on four rough substrates. (D) Profile changes of the Cu–Ag-EGaIn with different doping ratios in horizontal and vertical states. (E) 3D profile and micrographs of liquid metal lines with a minimum linewidth of ?50 μm. (F) Large-area and stretchable samples with complex patterns.

Figure 2. Surface characterization and adhesion tests of printed coating and Cu–Ag-EGaIn. (A) SEM images of the eight substrates. (B) SEM images of TPU on fabrics, toner, transferred toner, and a printed Cu–Ag-EGaIn line. (C) 3D profiles of TPU, knitted fabrics, TPU on fabrics, and toner. (D) Adhesion forces of the liquid metal measured on three substrates (knitted fabrics, TPU on fabrics, and toner). (E) Images of different separation states of Cu–Ag-EGaIn on three substrate samples. (F) Images of Cu–Ag-EGaIn droplets rolling down from three substrates.

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